ntegrated circuitry is becoming increasingly complex. These days a Pentium processor contains some 30 million transistors. And the magnetic structures found in hard drives measure just 10 to 20 nanometers across – less than a flu virus at 80 to 120 nanometers in diameter. Dimensions are rapidly approaching the realm of quantum physics and, already, researchers at the Fraunhofer Institute for Applied Solid State Physics IAF in Freiburg are applying themselves to the quantum technology challenges of tomorrow. Together with colleagues at the Max Planck Institute for Solid State Research, they are developing a quantum sensor that will be able to precisely measure the tiny magnetic fields we can expect to see in the next generation of hard discs. The sensor itself is just slightly larger than a nitrogen atom, with a synthetic diamond to act as a substrate.

Diamond has a variety of advantages quite apart from its considerable mechanical and chemical stability. For instance, one can implant foreign atoms such as boron or phosphorus, thereby turning the crystals into semiconductors. Diamond is also the perfect material for optical circuits. But perhaps its greatest attribute is its impressive thermal conductivity, with the strength of the carbon atom bonds ensuring that heat is rapidly dissipated.

Over the past decades, Fraunhofer IAF has developed optimized systems for producing diamonds. The process for mass production takes places in a plasma reactor, and Freiburg possesses many of these silver-colored devices. Plasma is ignited to generate temperatures of 800 to 900 degrees Celsius so that, when gas is fed into the chamber, diamond layers can form on the square-shaped substrate. The diamond crystals have an edge length of between three and eight millimeters, and are then separated from the substrate and polished using a laser.

Preparing the diamond to act as a magnetic detector

Manufacturing the innovative quantum sensor requires a particularly pure crystal, which has inspired further improvements in the process. For instance, in order to grow ultra-pure diamond layers, the methane that provides the carbon for the diamond is pre-filtered using a zirconium filter. On top of that, the gas must be isotopically pure, since only 12C–a stable isotope of the carbon atom–has zero nuclear spin, which is a prerequisite for the magnetic sensor later on. The hydrogen also undergoes a purification process, after which the ultra-pure single crystal diamond must be prepared for its role as a magnetic detector. Here there are two options: either you insert a single nitrogen atom into the extremely fine tip, or you add nitrogen at the final phase of the diamond production process. After that, the diamond tip is honed in oxygen plasma using an etching process in the institute's own cleanroom. The final result is an extremely fine diamond tip that resembles that of an atomic force microscope. The key to the whole design is the added nitrogen atom together with a neighboring vacancy in the crystal structure.

This combined nitrogen-vacancy center acts as the actual sensor, emitting light when it is exposed to a laser and microwaves. If there is a magnet nearby, it will vary in its light emission. Experts call this electron spin resonance spectroscopy. Not only can this technique detect magnetic fields with nanometer accuracy, it can determine their force as well, opening up an extraordinary range of applications. For instance, the tiny diamond tips can be used to monitor hard drive quality. These data storage devices are tightly packed and there are always tiny errors. The quantum sensor can identify defective data segments so that they are excluded from the disc reading and writing process. This reduces the defect rate, which is soaring as miniaturization continues apace, and cuts down on production costs.

Quantum sensors could measure brain activity

The tiny sensor can potentially be applied in a wide range of scenarios, since there are weak magnetic fields everywhere, even in the brain. "Whenever electrons move, they generate a magnetic field," says IAF expert Christoph Nebel. So when we think or feel, our brains are generating magnetic fields. Researchers are keen to localize this brain activity to determine the areas of the brain that are responsible for a certain function or feeling. This can be done directly by measuring brainwaves using electrodes, but the results are very imprecise. Magnetic field measurements offer far better results. However, the sensors in use at the moment have one significant disadvantage in that they must be cooled with liquid nitrogen. Drawing on the extreme thermal conductivity of diamond, the new technology can operate at room temperature without the need for any cooling. For this application, instead of using fine tips you would use tiny platelets that incorporate multiple nitrogen-vacancy centers. Each center supplies a point in the image and, together, a detailed picture.

Currently, however, Christoph Nebel and his team are focusing their attention on researching and optimizing diamond as a high-tech material. This application in quantum sensor technology is a promising beginning.

High hardness(ca.90Gpa)and wear-resisting performance

High volume modulus(1.2×1012N•m-2)

Highest thermal conductivity in room(2×1013W(m•K)-1)

Low compression ratio (8.3×1013m2 •N-1)

Extremely low thermal expansion coefficient (1×10-6K)

High transmission in every wave band both infrared and far infrared

High rate of sound conduction (17.5km•s-1)

Good insulation property (Resistivity in the room（ca. 1016Ω•cm）

It can be a semiconductor material after doping

Extremely wide width（5.4eV）

Good chemical inertness and biocompatibility

Some crystal surface shows low or negative electron affinity

Diamond, as one of the most special materials in natural world, is featured with the highest hardness, low friction coefficient, high elasticity modulus, high thermal conductivity, high insulation class, wide energy gap, great sound propagation rate and favorable chemical stability, which are presented in below Table. In spite of such unique features, the natural diamond has always been existed in the form of gem, with its variability and rareness sharply limiting its application. Luoyang Yuxin Diamond Co., Ltd’ s CVD Diamond film, on the other hand, integrates such physical and chemical properties, with lower cost than natural diamond and applicable to be made into various shapes, thus enjoying extensive application prospect in electronic industry, optical field and mechanical industry.